The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkynes+radicals / CF / Cobos(2018)_2000K_200-285nm(upper limits)

DATAFILE: CF_Cobos(2018)_2000K_200-285nm(upper limits).txt
NAME: fluoromethylidyne, fluorocarbyne
FORMULA: CF
AUTHOR(YEAR): Cobos(2018)
T: 2000K
λ: 200-285nm(upper limits)
BIBLIOGRAPHY: C.J. Cobos, G. Knight, L. Sölter, E. Tellbach, and J. Troe, "Experimental and modelling study of the multichannel thermal dissociations of CH3F and CH2F", Phys. Chem. Chem. Phys. 20, 2627-2636 (2018) DOI: 10.1039/c7cp07098e
COMMENTS: The thermal unimolecular dissociation of CH3F was studied in shock waves by monitoring the UV absorption of a dissociation product identified as CH2F

σ(CF) was obtained assuming complete dissociation of CH2F to CF+H2 or CF+2H, therefore only upper limits could be given

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